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  1. H0 without the sound horizon (or supernovae): A 2% measurement in DESI DR1

    The sound horizon scale rs is a key source of information for measurements of H0 from early-time data, and is therefore a common target of new physics proposed to solve the Hubble tension. We present a sub-2% measurement of the Hubble constant that is independent of this scale, using data from the first data release of the Dark Energy Spectroscopic Instrument (DESI DR1). Building on previous work, we remove dependency on the sound horizon size using a heuristic rescaling procedure at the power spectrum level. A key innovation is the inclusion of uncalibrated (agnostic to rs) post-reconstruction BAO measurements frommore » DESI DR1, as well as using the CMB acoustic scale ΞΈ* as a high-redshift anchor. Uncalibrated type-Ia supernovae are often included as an independent source of Ξ©m information; here we demonstrate the robustness of our results by additionally considering two supernova-independent alternative datasets. We find somewhat higher values of H0 relative to our previous work: 69.2+1.3-1.4, 70.3+1.4-1.2, and 69.6+1.3-1.8 km s-1 Mpc-1 respectively when including measurements from i) Planck/ACT CMB lensing Γ— unWISE galaxies, ii) the DES Year 3 6Γ—2pt analysis, and iii) Planck/ACT CMB lensing + the DES Year 5 supernova analysis. These remarkably consistent constraints achieve better than 2% precision; they are among the most stringent sound horizon-independent measurements from LSS to date, and provide a powerful avenue for probing the origin of the Hubble tension.« less
  2. Data Release 1 of the Dark Energy Spectroscopic Instrument

    In 2021 May the Dark Energy Spectroscopic Instrument (DESI) collaboration began a 5 yr spectroscopic redshift survey to produce a detailed map of the evolving three-dimensional structure of the Universe between z = 0 and z β‰ˆ 4. DESI’s principal scientific objectives are to place precise constraints on the equation of state of dark energy, the gravitationally driven growth of large-scale structure, and the sum of the neutrino masses, and to explore the observational signatures of primordial inflation. We present DESI DR1, which consists of all data acquired during the first 13 months of the DESI main survey, as well as amore » uniform reprocessing of the DESI Survey Validation data, which were previously made public in the DESI Early Data Release. The DR1 main survey includes high-confidence redshifts for 18.7M objects, of which 13.1M are spectroscopically classified as galaxies, 1.6M as quasars, and 4M as stars, making DR1 the largest sample of extragalactic redshifts ever assembled. We summarize the DR1 observations, the spectroscopic data-reduction pipeline and data products, large-scale structure catalogs, value-added catalogs, and describe how to access and interact with the data. In addition to fulfilling its core cosmological objectives with unprecedented precision, we expect DR1 to enable a wide range of transformational astrophysical studies and discoveries.« less
  3. Validation of the DESI DR2 Ly⁒ 𝛼 BAO analysis using synthetic datasets

    The second data release (DR2) of the Dark Energy Spectroscopic Instrument (DESI), containing data from the first three years of observations, doubles the number of Lyman-Ξ± (Ly Ξ±) forest spectra in DR1 and it provides the largest dataset of its kind. To ensure a robust validation of the baryonic acoustic oscillation (BAO) analysis using Ly Ξ± forests, we have made significant updates compared to DR1 to both the mocks and the analysis framework used in the validation. In particular, we present CoLoRe-QL, a new set of LyΞ± mocks that use a quasilinear input power spectrum to incorporate the nonlinear broadeningmore » of the BAO peak. Here, we have also increased the number of realizations used in the validation to 400, compared to the 150 realizations used in DR1. Finally, we present a detailed study of the impact of quasar redshift errors on the BAO measurement, and we compare different strategies to mask damped Lyman-Ξ± absorbers in our spectra. The BAO measurement from the Ly Ξ± dataset of DESI DR2 is presented in a companion publication.« less
  4. Reconciling the Different Apparent Decay Pathways for Iron(III) Tetraphenylporphyrin Chloride: Evidence for Excited State Branching

    Detailed understanding of the photophysical properties of metalloporphyrins is key to rationally exploiting them in a variety of applications ranging from photocatalysis to opto-magnetics. Previous studies of the ferric-tetraphenylporphyrin chloride have provided contradictory descriptions of the excited state evolution. Optical transient-absorption suggested initial formation of a ππ* excited state, followed by ligand-to-metal charge-transfer (LMCT) from the porphyrin ring and then decay on the ∼2 ps time scale to a metal-centered excited state that had a lifetime of ∼15 ps. In contrast, femtosecond extreme ultraviolet transient-absorption at the Fe M2,3-edge, while agreeing on the initial formation of an LMCT state, foundmore » evidence that this decayed in ∼2 ps to the ground state. Here, we have used K-edge transient X-ray absorption and X-ray emission, together with time-resolved X-ray solution scattering to explore this system. Based on these data, we propose a new model, consistent with both the earlier and the current data, in which photoexcited FeTPPCl evolves through three different states on the LMCT manifold, with the ∼2 ps decay now seen to involve a branching between return to the ground state (∼70%) and formation of a long-lived LMCT state (∼30%).« less
  5. Resistivity Distribution and Donor Properties of Antimony-Doped n-Type Czochralski Silicon Ingots

    We investigate antimony (Sb)-doped Czochralski-grown silicon as an alternative n-type substrate for photovoltaic applications, and characterize their axial resistivity distribution, donor properties, and mechanical strength. We find that Sb-doped ingots can achieve a more uniform resistivity distribution along the axial direction compared to P-doped counterparts. Dopant concentration profiles in P-doped ingots can be accurately modelled using the standard Scheil's equation, accounting only for dopant segregation during solidification. In contrast, modelling Sb-doped ingots requires consideration of both dopant segregation and evaporation effects to fit the dopant distribution accurately. Using electron paramagnetic resonance spectroscopy at 9 K, we observe two hyperfine linesmore » in P-doped samples, and six hyperfine lines for Sb121 and eight for Sb123 isotopes, with the number of hyperfine lines governed by the nuclear spins. We further identify two-atom Sb clustering in the Sb-doped wafers, confirmed through simulations of the additional weak electron paramagnetic resonance peaks. Finally, we find that 140 ..mu..m as-cut planar Sb-doped wafers exhibit slightly higher mechanical strength compared to P-doped wafers.« less
  6. Cosmological implications of DESI DR2 BAO measurements in light of the latest ACT DR6 CMB data

    We report cosmological results from the Dark Energy Spectroscopic Instrument (DESI) measurements of baryon acoustic oscillations (BAO) when combined with recent data from the Atacama Cosmology Telescope (ACT). By jointly analyzing ACT and Planck data and applying conservative cuts to overlapping multipole ranges, we assess how different π‘ƒβ’π‘™β’π‘Žβ’π‘›β’π‘β’π‘˜ + ACT dataset combinations affect consistency with DESI. While ACT alone exhibits a tension with DESI exceeding 3⁒𝜎 within the Λ⁒ CDM model, this discrepancy is reduced when ACT is analyzed in combination with Planck. For our baseline DESI DR2 BAO + π‘ƒβ’π‘™β’π‘Žβ’π‘›β’π‘β’π‘˜ P⁒R⁒4 + ACT likelihood combination, the preference for evolvingmore » dark energy over a cosmological constant is about 3⁒𝜎, increasing to over 4⁒𝜎 with the inclusion of type Ia supernova data. While the dark energy results remain quite consistent across various combinations of Planck and ACT likelihoods with those obtained by the DESI collaboration, the constraints on neutrino mass are more sensitive, ranging from βˆ‘π‘šπœˆ< 0.061 eV in our baseline analysis, to βˆ‘π‘šπœˆ < 0.077 eV (95% confidence level) in the CMB likelihood combination chosen by ACT when imposing the physical prior βˆ‘π‘šπœˆ > 0 eV.« less
  7. Constraints on neutrino physics from DESI DR2 BAO and DR1 full shape

    The Dark Energy Spectroscopic Instrument (DESI) Collaboration has obtained robust measurements of baryon acoustic oscillations in the redshift range 0.1 < 𝑧 < 4.2, based on the Lyman-𝛼 forest and galaxies from data release 2. We combine these measurements with cosmic microwave background (CMB) data from Planck and the Atacama Cosmology Telescope to place our tightest constraints yet on the sum of neutrino masses. Assuming the cosmological Λ⁒ CDM model and three degenerate neutrino states, we find βˆ‘π‘šπœˆ < 0.0642 eV (95%) with a marginalized error of 𝜎⁑(βˆ‘π‘šπœˆ) = 0.020 eV. We also constrain the effective number of neutrino species,more » finding 𝑁eff = 3.2⁒3$$^{+0.35}_{βˆ’0.34}$$ (95%), in line with the Standard Model prediction. When accounting for neutrino oscillation constraints, we find a preference for the normal mass ordering and an upper limit on the lightest neutrino mass of π‘šπ‘™ < 0.023 eV (95%). However, we determine using frequentist and Bayesian methods that our constraints are in tension with the lower limits derived from neutrino oscillations. Correcting for the physical boundary at zero mass, we report a 95% Feldman-Cousins upper limit of βˆ‘π‘šπœˆ < 0.053 eV, breaching the lower limit from neutrino oscillations. Considering a more general Bayesian analysis with an effective cosmological neutrino mass parameter, βˆ‘π‘šπœˆ,eff, that allows for negative energy densities and removes unsatisfactory prior weight effects, we derive constraints that are in 3⁒𝜎 tension with the same oscillation limit, while the error rises to 𝜎⁑(βˆ‘π‘šπœˆ,eff) = 0.053 eV. In the absence of unknown systematics, this finding could be interpreted as a hint of new physics not necessarily related to neutrinos. The preference of DESI and CMB data for an evolving dark energy model offers one possible solution. In the 𝑀0β’π‘€π‘Žβ’CDM model, we find βˆ‘π‘šπœˆ < 0.163 eV (95%), relaxing the neutrino tension. These constraints all rely on the effects of neutrinos on the cosmic expansion history. Using full-shape power spectrum measurements of data release 1 galaxies, we place complementary constraints that rely on neutrino free streaming. Our strongest such limit in Ξ› ⁒CDM, using selected CMB priors, is βˆ‘π‘šπœˆ < 0.193 eV (95%).« less
  8. Construction of the damped Ly⁒𝛼 absorber catalog for DESI DR2 Ly⁒𝛼 BAO

    We present the Damped Ly⁒𝛼 Toolkit for automated detection and characterization of damped Ly⁒𝛼 absorbers (DLAs) in quasar spectra. Our method uses quasar spectral templates with and without absorption from intervening DLAs to reconstruct observed quasar forest regions. The best-fitting model determines whether a DLA is present while estimating the redshift and HI column density. With an optimized quality cut on detection significance (Ξ”β’πœ’$$^{2}_{π‘Ÿ}$$ >0.03), the technique achieves an estimated 80% purity and 79% completeness when evaluated on simulated spectra with S/N>2 that are free of broad absorption lines (BALs). We provide a catalog containing candidate DLAs from the DLAmore » Toolkit detected in DESI DR1 quasar spectra, of which 21 719 were found in S/N>2 spectra with predicted log10⁑(𝑁𝙷𝙸)>20.3 and detection significance Ξ”β’πœ’$$^{2}_{π‘Ÿ}$$ >0.03. We compare the Damped Ly⁒𝛼 Toolkit to two alternative DLA finders based on a convolutional neural network and Gaussian process models. We present a strategy for combining these three techniques to produce a high-fidelity DLA catalog from DESI DR2 for the Ly⁒𝛼 forest baryon acoustic oscillation measurement. The combined catalog contains 41 152 candidate DLAs with log10⁑(𝑁𝙷𝙸)>20.3 from quasar spectra with S/N>2. We estimate this sample to be approximately 85% pure and 79% complete when BAL quasars are excluded.« less
  9. Extended dark energy analysis using DESI DR2 BAO measurements

    We conduct an extended analysis of dark energy constraints, in support of the findings of the Dark Energy Spectroscopic Instrument (DESI) second data release cosmology key paper, including DESI data, Planck cosmic microwave background observations, and three different supernova compilations. Using a broad range of parametric and nonparametric methods, we explore the dark energy phenomenology and find consistent trends across all approaches, in good agreement with the 𝑀0β’π‘€π‘Žβ’CDM (cold dark matter) key paper results. Even with the additional flexibility introduced by nonparametric approaches, such as binning and Gaussian processes, we find that extending Λ⁒ CDM to include a two-parameter 𝑀⁑(𝑧)more » is sufficient to capture the trends present in the data. Finally, we examine three dark energy classes with distinct dynamics, including quintessence scenarios satisfying 𝑀 β‰₯ βˆ’1, to explore what underlying physics can explain such deviations. The current data indicate a clear preference for models that feature a phantom crossing; although alternatives lacking this feature are disfavored, they cannot yet be ruled out. Our analysis confirms that the evidence for dynamical dark energy, particularly at low redshift (𝑧 ≲ 0.3), is robust and stable under different modeling choices.« less
  10. Validation of the DESI DR2 measurements of baryon acoustic oscillations from galaxies and quasars

    The Dark Energy Spectroscopic Instrument (DESI) Data Release 2 (DR2) galaxy and quasar clustering data represents a significant expansion of data from Data Release 1 (DR1), providing improved statistical precision in baryon acoustic oscillation (BAO) constraints across multiple tracers, including bright galaxies, luminous red galaxies, emission line galaxies, and quasars. In this paper, we validate the BAO analysis of DR2. We present the results of robustness tests on the blinded DR2 data and, after unblinding, consistency checks on the unblinded DR2 data. All results are compared with those obtained from a suite of mock catalogs that replicate the selection andmore » clustering properties of the DR2 sample. We confirm the consistency of DR2 BAO measurements with DR1 while achieving a reduction in statistical uncertainties due to the increased survey volume and completeness. The combined BAO precision, including both statistical and systematic errors, improves from ∼0.52% in DR1 to 0.30% in DR2β€”a factor of 1.7 gain. We assess the impact of analysis choices, including different data vectors (correlation function vs power spectrum), modeling approaches and systematics treatments, and an assumption of the Gaussian likelihood, finding that our BAO constraints are stable across these variations and assumptions with a few minor refinements to the baseline setup of the DR1 BAO analysis. We summarize a series of pre-unblinding tests that confirmed the readiness of our analysis pipeline, the final systematic errors, and the DR2 BAO analysis baseline. The successful completion of these tests led to the unblinding of the DR2 BAO measurements, ultimately leading to the DESI DR2 cosmological analysis, with their implications for the expansion history of the Universe and the nature of dark energy presented in the DESI key paper (companion paper).« less
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